In recent years, China’s economic growth and labor productivity have been improved significantl when the digital economy with Internet, big data and artificial intelligence as the core production factors and innovation driven as the strategic support has gradually risen to the national strategy. The composition of capital technology has always maintained a steady rising trend, while the composition of capital organic and capital value has shown a fluctuating decline. The proportion of labor remuneration has been in a low-level, stable and slow growth state in the national income distribution pattern for a long time. Thus, how to improve the proportion of labor remuneration has increasingly become the bottleneck of high-quality economic development. Based on the theoretical analysis of the relationship between the three major components of capital and the proportion of labor remuneration, this paper studies the influence of the new changes of the three components of capital on the proportion of labor remuneration in the era of digital economy, which found that the composition of capital and technology is affected by labor productivity and employment quantity, and then affects the ratio of labor remuneration. The influence of capital value composition on labor remuneration ratio is closely related to wage level. The difference in the ratio of labor compensation is also observed when the organic composition of capital changes with the level of economic development. Therefore, it is necessary to develop a precise differentiated employment policies in combination with the employment absorption characteristics of the three industries while improving labor productivity. Meanwhile, it is essential to form an olive type distribution structure with a large middle and small ends, which expends the medium income group specific weight and increases the remuneration for the low income group. Moreover, it needs to explore the “dual” ownership structure change of material and mental production material, combined with the change of organic composition of capital characteristics to rationally distribute the two elements of labor and capital. The promotion of equal access to public services and the increment of investment in affordable human capital can support mutual enrichment in economically high-quality development.